{CoIII2DyIII2} single molecule magnet with two resolved thermal activated magnetization relaxation pathways at zero field

Alejandro V. Funes; Luca Carrella; Eva Rentschler; Pablo Alborés

doi:10.1039/C3DT52765D

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

{Co^III₂Dy^III₂} single molecule magnet with two resolved thermal activated magnetization relaxation pathways at zero field†

Alejandro V. Funes,^a Luca Carrella,^b Eva Rentschler^b and Pablo Alborés*^a

Author affiliations

* Corresponding authors

^a Departamento de Química Inorgánica, Analítica y Química Física/INQUIMAE (CONICET), Facultad de Ciencias Exactas y Naturales Universidad de Buenos Aires, Pabellón 2, Ciudad Universitaria, C1428EHA Buenos Aires, Argentina
E-mail: albores@qi.fcen.uba.ar
Fax: +54 1145763341
Tel: +54 1145763380

^b Institute of Inorganic and Analytical Chemistry, Johannes Gutenberg – University of Mainz, Duesbergweg 10-14, D-55128 Mainz, Germany

Abstract

The new complex [Co^III₂Dy^III₂(OMe)₂(teaH)₂(Piv)₆] in the {Co^III₂Dy^III₂} family, shows two well resolved thermal activated magnetization relaxation pathways under AC experiments in zero DC field. Fitted crystal field parameters suggest that the origin of these two pathways relies on two different excited m_J sub-levels.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C3DT52765D
Article type: Communication
Submitted: 03 Oct 2013
Accepted: 13 Nov 2013
First published: 19 Nov 2013

Download Citation

Dalton Trans., 2014,43, 2361-2364

Permissions

Request permissions

{Co^III₂Dy^III₂} single molecule magnet with two resolved thermal activated magnetization relaxation pathways at zero field

A. V. Funes, L. Carrella, E. Rentschler and P. Alborés, Dalton Trans., 2014, 43, 2361 DOI: 10.1039/C3DT52765D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions