Issue 4, 2014
From the journal:

Dalton Transactions

Solid state anion–π interactions involving polyhalides†

Michael Giese,‡a   Markus Albrecht,*a   Christian Bohnen,a   Tatjana Repenko,a   Arto Valkonen§b  and  Kari Rissanen*b  

* Corresponding authors

a Institut für Organische Chemie, RWTH Aachen, Landoltweg 1, 52074 Aachen, Germany
E-mail: markus.albrecht@oc.rwth-aachen.de
Fax: +49 241 809 2385
Tel: +49 241 809 4678

b Department of Chemistry, Nanoscience Center, University of Jyväskylä, Survontie 9, 40014 Jyväskylä, Finland
E-mail: kari.t.rissanen@jyu.fi
Fax: +358 14 260 2672
Tel: +358 50 562 3721

Abstract

The stabilization of polyhalides in the solid state with the support of electron-deficient pentafluorophenyl groups is described. Furthermore, a synthetic approach towards the sensitive tetraiodide dianion is described and ESI mass spectrometric evidence for its presence in solution is reported.

Graphical abstract: Solid state anion–π interactions involving polyhalides

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Article information

DOI
https://doi.org/10.1039/C3DT52960F
Article type
Paper
Submitted
21 Oct 2013
Accepted
01 Nov 2013
First published
04 Nov 2013

Dalton Trans., 2014,43, 1873-1880

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Solid state anion–π interactions involving polyhalides

M. Giese, M. Albrecht, C. Bohnen, T. Repenko, A. Valkonen and K. Rissanen, Dalton Trans., 2014, 43, 1873 DOI: 10.1039/C3DT52960F

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