Issue 14, 2014
From the journal:

Dalton Transactions

Oxacalix[4]arene-supported di-, tetra- and undecanuclear copper(ii) clusters†‡

Robyn E. Fairbairn,a   Ross McLellan,a   Ruaraidh D. McIntosh,a   Maria A. Palacios,b   Euan K. Brechin*b  and  Scott J. Dalgarno*a  

* Corresponding authors

a Institute of Chemical Sciences, Heriot-Watt University, Riccarton, Edinburgh, Scotland, UK
E-mail: S.J.Dalgarno@hw.ac.uk
Fax: +44(0)131 451 3180
Tel: +44(0)131 451 8025

b EaStCHEM School of Chemistry, University of Edinburgh, West Mains Road, Edinburgh, Scotland, UK
E-mail: ebrechin@staffmail.ed.ac.uk
Fax: +44(0)131 650 6453
Tel: +44(0)131 650 7545

Abstract

Oxacalix[4]arenes containing either one or two oxa-bridges afford di and undecanuclear CuII clusters respectively upon reaction with cupric nitrate under facile conditions. Variation in reaction conditions results in formation of a tetranuclear CuII cluster with mono-oxacalix[4]arene, representing a structural expansion of the dinuclear assembly.

Graphical abstract: Oxacalix[4]arene-supported di-, tetra- and undecanuclear copper(ii) clusters

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Article information

DOI
https://doi.org/10.1039/C3DT53088D
Article type
Paper
Submitted
31 Oct 2013
Accepted
04 Dec 2013
First published
12 Dec 2013

Dalton Trans., 2014,43, 5292-5298

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Oxacalix[4]arene-supported di-, tetra- and undecanuclear copper(II) clusters

R. E. Fairbairn, R. McLellan, R. D. McIntosh, M. A. Palacios, E. K. Brechin and S. J. Dalgarno, Dalton Trans., 2014, 43, 5292 DOI: 10.1039/C3DT53088D

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