Issue 8, 2013

A palladium complex with functionalized β-cyclodextrin: a promising catalyst featuring recognition abilities for Suzuki–Miyaura coupling reactions in water

Abstract

A water-soluble palladium complex (PdLn@β-CD) was designed and prepared based on functionalized β-cyclodextrin. It showed high turnover numbers (TONs) and turnover frequencies (TOFs) of up to 9.9 × 108 and 4.9 × 108 h−1, respectively, in aqueous Suzuki–Miyaura coupling reactions. The detailed reason for the excellent catalytic activity was studied.

Graphical abstract: A palladium complex with functionalized β-cyclodextrin: a promising catalyst featuring recognition abilities for Suzuki–Miyaura coupling reactions in water

Supplementary files

Article information

Article type
Communication
Submitted
05 Apr 2013
Accepted
03 Jun 2013
First published
04 Jun 2013

Green Chem., 2013,15, 2081-2085

A palladium complex with functionalized β-cyclodextrin: a promising catalyst featuring recognition abilities for Suzuki–Miyaura coupling reactions in water

G. Zhang, Y. Luan, X. Han, Y. Wang, X. Wen, C. Ding and J. Gao, Green Chem., 2013, 15, 2081 DOI: 10.1039/C3GC40645H

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