Issue 12, 2013
From the journal:

Green Chemistry

Practical metal- and additive-free methods for radical-mediated reduction and cyclization reactions†

Hao Jiang,a   Jesper R. Bak,a   Francisco Javier López-Delgadoa  and  Karl Anker Jørgensen*a  

* Corresponding authors

a Center for Catalysis, Department of Chemistry, Aarhus University, Langelandsgade 140, DK-8000 Aarhus C, Denmark
E-mail: kaj@chem.au.dk
Fax: +45 86 19 61 99
Tel: +45 87155956

Abstract

Two facile, metal- and additive-free protocols for radical dehalogenation, deoxygenation and cyclization reactions are reported. Irradiation by household fluorescent light bulbs or the presence of an air atmosphere is shown to initiate the desired reactions, thus providing highly practical reaction setups for radical-mediated reductions and cyclizations.

Graphical abstract: Practical metal- and additive-free methods for radical-mediated reduction and cyclization reactions

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Article information

DOI
https://doi.org/10.1039/C3GC41520A
Article type
Paper
Submitted
29 Jul 2013
Accepted
28 Oct 2013
First published
29 Oct 2013

Green Chem., 2013,15, 3355-3359

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Practical metal- and additive-free methods for radical-mediated reduction and cyclization reactions

H. Jiang, J. R. Bak, F. J. López-Delgado and K. A. Jørgensen, Green Chem., 2013, 15, 3355 DOI: 10.1039/C3GC41520A

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