Issue 3, 2014

The effect of temperature on interhalogen interactions in a series of isostructural organic systems

Abstract

The thermal expansion behaviors of two sets, the guest-free forms and the ethyl acetate solvates, of interhalogen interaction mediated isostructural networks of 2,4,6-triethyl-1,3,5-tris(4-halophenoxy)methylbenzene (halo = Cl, Br and I) have been studied. In both of the series, the order of increase in interhalogen distances with increasing temperature is I⋯I < Br⋯Br < Cl⋯Cl which is actually the reverse order of interhalogen interaction strength.

Graphical abstract: The effect of temperature on interhalogen interactions in a series of isostructural organic systems

Supplementary files

Article information

Article type
Letter
Submitted
11 Nov 2013
Accepted
07 Jan 2014
First published
09 Jan 2014

New J. Chem., 2014,38, 897-901

Author version available

The effect of temperature on interhalogen interactions in a series of isostructural organic systems

V. G. Saraswatula and B. K. Saha, New J. Chem., 2014, 38, 897 DOI: 10.1039/C3NJ01395B

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