A new non-centrosymmetric adamantanoid metal cluster has been synthesized by combining the macrocyclic K222 cryptand and ZnI2. Its solid-state crystal-to-polycrystalline transformation involves only the anionic adamantanoid cluster, while the cationic cryptand remains virtually unchanged as shown by single crystal and powder X-ray crystallography.
J. Martí-Rujas and M. Cametti, New J. Chem., 2014, 38, 1385 DOI: 10.1039/C3NJ01400B
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