Issue 19, 2014

Catalytic amounts of triarylaminium salt initiated aerobic oxidative coupling of N-aryl tetrahydroisoquinolines

Abstract

A novel stable radical cation triarylaminium salt able to induce aerobic oxidative α-C–H functionalization of tertiary amines in catalytic amounts has been developed. The reaction is performed in the absence of any other additives under mild conditions and only requires atmosphere air as a sustainable co-oxidant.

Graphical abstract: Catalytic amounts of triarylaminium salt initiated aerobic oxidative coupling of N-aryl tetrahydroisoquinolines

Supplementary files

Article information

Article type
Paper
Submitted
09 Dec 2013
Accepted
11 Mar 2014
First published
12 Mar 2014

Org. Biomol. Chem., 2014,12, 3123-3128

Catalytic amounts of triarylaminium salt initiated aerobic oxidative coupling of N-aryl tetrahydroisoquinolines

C. Huo, C. Wang, M. Wu, X. Jia, X. Wang, Y. Yuan and H. Xie, Org. Biomol. Chem., 2014, 12, 3123 DOI: 10.1039/C3OB42454E

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