Issue 10, 2014
From the journal:

Polymer Chemistry

Liquid acid-catalysed fabrication of nanoporous 1,3,5-triazine frameworks with efficient and selective CO2 uptake†

Shaohui Xiong,‡a   Xian Fu,‡a   Lu Xiang,a   Guipeng Yu,*a   Jianguo Guan,b   Zhonggang Wang,*c   Yong Du,d   Xiang Xiongd  and  Chunyue Pan*a  

* Corresponding authors

a Key Laboratory of Resources Chemistry of Nonferrous Metals Ministry of Education, College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China
E-mail: gilbertyu@csu.edu.cn
Fax: +8673188876626
Tel: +86 73188836961

b State Key Laboratory of Advanced Technology For Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China

c Department of Polymer Science & Materials, Dalian University of Technology, Dalian 116012, China
E-mail: zgwang@dlut.edu.cn
Fax: +86 41184986096
Tel: +86 41184986096

d State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China

Abstract

New classes of nanoporous organic polymers based on 1,3,5-triazine units (NOP-1–6) were synthesized via a straightforward, methane-sulfonic acid-catalysed, cost-effective Friedel–Crafts reaction of 2,4,6-trichloro-1,3,5-triazine and tetrahedral building blocks. Among them, NOP-3 with a Brunauer–Emmet–Teller (BET) specific surface area up to 894 m2 g−1 and the total volume exceeding 0.41 m3 g−1 exhibits good hydrogen adsorption capacity (up to 1.14 wt% at 77 K/1.0 bar) and high carbon dioxide uptake (up to 11.03 wt% at 273 K/1.0 bar). Furthermore, it presents an effective selectivity for CO2 adsorption (NOP-6, CO2/N2 selectivity 38.7 at 273 K/1.0 bar), demonstrating potential applications in gas adsorption and separation.

Graphical abstract: Liquid acid-catalysed fabrication of nanoporous 1,3,5-triazine frameworks with efficient and selective CO2 uptake

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3PY01471A
Article type
Paper
Submitted
22 Oct 2013
Accepted
18 Jan 2014
First published
24 Jan 2014

Polym. Chem., 2014,5, 3424-3431

Permissions

Request permissions

Liquid acid-catalysed fabrication of nanoporous 1,3,5-triazine frameworks with efficient and selective CO2 uptake

S. Xiong, X. Fu, L. Xiang, G. Yu, J. Guan, Z. Wang, Y. Du, X. Xiong and C. Pan, Polym. Chem., 2014, 5, 3424 DOI: 10.1039/C3PY01471A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements