Magneto-chiral dichroism in chiral mixed (phthalocyaninato)(porphyrinato) rare earth triple-decker SMMs

Kang Wang; Suyuan Zeng; Hailong Wang; Jianmin Dou; Jianzhuang Jiang

doi:10.1039/C3QI00097D

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Magneto-chiral dichroism in chiral mixed (phthalocyaninato)(porphyrinato) rare earth triple-decker SMMs†

Kang Wang,^a Suyuan Zeng,^b Hailong Wang,^a Jianmin Dou^b and Jianzhuang Jiang*^a

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* Corresponding authors

^a Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, Department of Chemistry, University of Science and Technology Beijing, Beijing 100083, China
E-mail: jianzhuang@ustb.edu.cn

^b Department of Chemistry, Liaocheng University, Liaocheng, China

Abstract

Two new chiral mixed (phthalocyaninato)(porphyrinato) rare earth triple-decker complexes with both (R)- and (S)-enantiomers were synthesized and structurally characterized. The significant magneto-chiral cross effect revealed for the dysprosium compound suggests the great potential of sandwich-type tetrapyrrole rare earth systems in the research field of magneto-chiral dichroism.

This article is part of the themed collection: HOT articles in Inorganic Chemistry Frontiers for 2014

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DOI: https://doi.org/10.1039/C3QI00097D
Article type: Communication
Submitted: 06 Dec 2013
Accepted: 14 Jan 2014
First published: 27 Jan 2014

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Inorg. Chem. Front., 2014,1, 167-171

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Magneto-chiral dichroism in chiral mixed (phthalocyaninato)(porphyrinato) rare earth triple-decker SMMs

K. Wang, S. Zeng, H. Wang, J. Dou and J. Jiang, Inorg. Chem. Front., 2014, 1, 167 DOI: 10.1039/C3QI00097D

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Inorganic Chemistry Frontiers

Magneto-chiral dichroism in chiral mixed (phthalocyaninato)(porphyrinato) rare earth triple-decker SMMs†

Abstract

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Magneto-chiral dichroism in chiral mixed (phthalocyaninato)(porphyrinato) rare earth triple-decker SMMs

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