Issue 22, 2013
From the journal:

RSC Advances

Design and synthesis of β-multi-substituted push–pull porphyrins†

Jing Chen,a   Ke-Lai Li,b   Yong Guo,a   Chao Liu,a   Can-Cheng Guo*b  and  Qing-Yun Chen*ab  

* Corresponding authors

a Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, P. R. China
E-mail: chenqy@sioc.ac.cn
Fax: +86 21 64166128
Tel: +86 21 54925196

b College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, P. R. China

Abstract

A novel group of β-multi-substituted push–pull porphyrins (1, 2 and 3) has been designed and synthesized. Only one tautomer was observed for each of them and electron-withdrawing (Br, CF3, –(CF)4−) and -donating (MeO) groups within those porphyrins were believed to be out of the major delocalization pathway.

Graphical abstract: Design and synthesis of β-multi-substituted push–pull porphyrins

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Article information

DOI
https://doi.org/10.1039/C3RA40308D
Article type
Communication
Submitted
21 Jan 2013
Accepted
22 Apr 2013
First published
23 Apr 2013

RSC Adv., 2013,3, 8227-8231

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Design and synthesis of β-multi-substituted push–pull porphyrins

J. Chen, K. Li, Y. Guo, C. Liu, C. Guo and Q. Chen, RSC Adv., 2013, 3, 8227 DOI: 10.1039/C3RA40308D

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