Issue 24, 2013
From the journal:

RSC Advances

Regioselective 2,6-dihalogenation of BODIPYs in 1,1,1,3,3,3-hexafluoro-2-propanol and preparation of novel meso-alkyl polymeric BODIPY dyes†

Liang Wang,a   Jian-Wei Wang,a   Ai-jun Cui,a   Xiao-Xiao Cai,a   Yan Wan,a   Qun Chen,a   Ming-Yang He*a  and  Wei Zhang*b  

* Corresponding authors

a Jiangsu Province Key Laboratory of Fine Petro-Chemical Technology, Changzhou University, Changzhou 213164, P. R. China
E-mail: lwcczu@126.com
Fax: +86-519-86330251
Tel: +86-(0)13961477422

b Department of Chemistry, University of Massachusetts Boston, MA 02125, USA
E-mail: wei2.zhang@umb.edu

Abstract

Regioselective 2,6-halogenation of BODIPYs in hexafluoro-2-propanol (HFIP) afforded products in less than 5 min. Halogenated BODIPYs were subjected to Pd-catalyzed cross-coupling reactions to form novel meso-alkyl polymeric BODIPY dyes.

Graphical abstract: Regioselective 2,6-dihalogenation of BODIPYs in 1,1,1,3,3,3-hexafluoro-2-propanol and preparation of novel meso-alkyl polymeric BODIPY dyes

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Article information

DOI
https://doi.org/10.1039/C3RA41298A
Article type
Communication
Submitted
08 Jan 2013
Accepted
03 Apr 2013
First published
05 Apr 2013

RSC Adv., 2013,3, 9219-9222

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Regioselective 2,6-dihalogenation of BODIPYs in 1,1,1,3,3,3-hexafluoro-2-propanol and preparation of novel meso-alkyl polymeric BODIPY dyes

L. Wang, J. Wang, A. Cui, X. Cai, Y. Wan, Q. Chen, M. He and W. Zhang, RSC Adv., 2013, 3, 9219 DOI: 10.1039/C3RA41298A

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