Issue 29, 2013
From the journal:

RSC Advances

Highly efficient and practical synthesis of functionalized 1,5-dienes via Pd(ii)-catalyzed halohomoallylation of alkynes†

Jianxiao Li,a   Shaorong Yang,*a   Liangbin Huang,a   Huoji Chena  and  Huanfeng Jiang*a  

* Corresponding authors

a School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, China
E-mail: jianghf@scut.edu.cn, lisryang@scut.edu.cn
Fax: +8620-87112906
Tel: +8620-87112906

Abstract

A Pd-catalyzed coupling of alkynes with homoallyl alcohols in ionic liquids has been reported, providing a practical, efficient, and versatile method for the synthesis of functionalized (1E)- or (1Z)-1,5-dienes in moderate to good yields. This reaction represents a rare instance of direct homoallylation of homoallyl alcohols.

Graphical abstract: Highly efficient and practical synthesis of functionalized 1,5-dienes via Pd(ii)-catalyzed halohomoallylation of alkynes

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Article information

DOI
https://doi.org/10.1039/C3RA41690A
Article type
Communication
Submitted
09 Apr 2013
Accepted
23 May 2013
First published
24 May 2013

RSC Adv., 2013,3, 11529-11532

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Highly efficient and practical synthesis of functionalized 1,5-dienes via Pd(II)-catalyzed halohomoallylation of alkynes

J. Li, S. Yang, L. Huang, H. Chen and H. Jiang, RSC Adv., 2013, 3, 11529 DOI: 10.1039/C3RA41690A

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