Issue 27, 2013
From the journal:

RSC Advances

Post-synthetic immobilization of palladium complexes on metal–organic frameworks – a new concept for the design of heterogeneous catalysts for Heck reactions†

Meike A. Gotthardt,a   Angela Beilmann,a   Roland Schoch,b   Julia Engelkea  and  Wolfgang Kleist*ac  

* Corresponding authors

a Karlsruhe Institute of Technology (KIT), Institute for Chemical Technology and Polymer Chemistry, Engesserstr. 20, D-76128 Karlsruhe, Germany
E-mail: wolfgang.kleist@kit.edu
Fax: +49 721 608 44820
Tel: +49 721 608 47989

b TU Kaiserslautern, Fachbereich Chemie, Erwin-Schrödinger-Str. 54, D-67663 Kaiserslautern, Germany

c Karlsruhe Institute of Technology (KIT), Institute of Catalysis Research and Technology, Hermann-von-Helmholtz-Platz 1, D-76344 Eggenstein-Leopoldshafen, Germany

Abstract

MIL-53-NH2(Al) was modified in a two-step post-synthetic reaction using maleic anhydride and palladium acetate. The resulting Pd-containing frameworks were used as catalysts in Heck-type CC coupling reactions where they exhibited high conversion and selectivity. The results of leaching tests indicate that the reaction is partly catalyzed heterogeneously.

Graphical abstract: Post-synthetic immobilization of palladium complexes on metal–organic frameworks – a new concept for the design of heterogeneous catalysts for Heck reactions

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Article information

DOI
https://doi.org/10.1039/C3RA42105H
Article type
Communication
Submitted
19 Feb 2013
Accepted
13 May 2013
First published
14 May 2013

RSC Adv., 2013,3, 10676-10679

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Post-synthetic immobilization of palladium complexes on metal–organic frameworks – a new concept for the design of heterogeneous catalysts for Heck reactions

M. A. Gotthardt, A. Beilmann, R. Schoch, J. Engelke and W. Kleist, RSC Adv., 2013, 3, 10676 DOI: 10.1039/C3RA42105H

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