Issue 44, 2013
From the journal:

RSC Advances

A monophosphoryl copillar[5]arene: synthesis and host–guest complexation with alkanols†

Yu Chen,a   Minqing He,a   Boqi Li,a   Lingyun Wang,a   Herbert Meier*b  and  Derong Cao*a  

* Corresponding authors

a School of Chemistry and Chemical Engineering, State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou 510641, China
E-mail: drcao@scut.edu.cn
Fax: +86 20 87110245
Tel: +86 20 87110245

b Institute of Organic Chemistry, University of Mainz, Duesbergweg 10-14, 55099 Mainz, Germany

Abstract

A monophosphoryl copillar[5]arene 1 was prepared. The introduction of the phosphoryl group remarkably promoted the binding affinity of 1 with alkanols and alkanediols in comparison with 1,4-dimethoxypillar[5]arene. Thus 1 can form a stable 1 : 1 host–guest complex with alkanols in CDCl3.

Graphical abstract: A monophosphoryl copillar[5]arene: synthesis and host–guest complexation with alkanols

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Article information

DOI
https://doi.org/10.1039/C3RA43744B
Article type
Communication
Submitted
19 Jul 2013
Accepted
24 Sep 2013
First published
25 Sep 2013

RSC Adv., 2013,3, 21405-21408

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A monophosphoryl copillar[5]arene: synthesis and host–guest complexation with alkanols

Y. Chen, M. He, B. Li, L. Wang, H. Meier and D. Cao, RSC Adv., 2013, 3, 21405 DOI: 10.1039/C3RA43744B

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