Issue 11, 2014

Triphenylamine-containing microporous organic copolymers for hydrocarbons/water separation

Abstract

Two novel porous copolymers PBP-N-25 and PBP-N-50 were synthesized from triphenylamine and 4,4′-bis(chloromethyl)biphenyl using a combination of oxidative polymerization and Friedel–Crafts alkylation process promoted by anhydrous FeCl3. The polymers were predominantly microporous, with apparent BET surface areas of 1362 m2 g−1 for PBP-N-25 and 1338 m2 g−1 for PBP-N-50. PBP-N-25 and PBP-N-50 possessed benzene vapor uptakes of 94.1 wt% and 107.3 wt% and cyclohexane vapor uptakes of 95.3 wt% and 83.8 wt%, while the water vapor uptakes were only 1.7 wt% and 1.2 wt%, respectively. The large amount of phenyl and methylene linkers resulted in the polymers' hydrophobicity and affinity toward aromatic and aliphatic compounds. The benzene/water vapor selectivities of PBP-N-25 and PBP-N-50 were as high as 53.5 and 63.6. Monolithic polymer M-PBP-N-25 with an apparent BET surface area of 551 m2 g−1 was prepared, which exhibited a good performance for oil/water separation. Owing to its hydrophobic nature and low density, the monolith was floating on the surface of water before and after collecting all of the oil from water. After removing the monolith from the surface, oil and water separated instantly.

Graphical abstract: Triphenylamine-containing microporous organic copolymers for hydrocarbons/water separation

Supplementary files

Article information

Article type
Paper
Submitted
06 Sep 2013
Accepted
13 Nov 2013
First published
14 Nov 2013

RSC Adv., 2014,4, 5568-5574

Triphenylamine-containing microporous organic copolymers for hydrocarbons/water separation

Y. Yang, Q. Zhang, S. Zhang and S. Li, RSC Adv., 2014, 4, 5568 DOI: 10.1039/C3RA44919J

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