Issue 25, 2014

Direct carboxylation of allylic halides with carbon dioxide in the presence of indium

Abstract

A highly regioselective indium-mediated allylation of carbon dioxide starting from simple allylic halides (X = I, Br, Cl) has been developed. No transition metal catalyst is needed and an inert atmosphere is not necessary. The reaction tolerates a wide range of synthetically attractive functional groups with a very high branched regioselectivity.

Graphical abstract: Direct carboxylation of allylic halides with carbon dioxide in the presence of indium

Supplementary files

Article information

Article type
Communication
Submitted
08 Jan 2014
Accepted
29 Jan 2014
First published
31 Jan 2014

Chem. Commun., 2014,50, 3285-3287

Direct carboxylation of allylic halides with carbon dioxide in the presence of indium

B. Miao and S. Ma, Chem. Commun., 2014, 50, 3285 DOI: 10.1039/C4CC00148F

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