Issue 52, 2014
From the journal:

Chemical Communications

High CO2/N2 and CO2/CH4 selectivity in a chiral metal–organic framework with contracted pores and multiple functionalities†

Xiaoxia Lv,ab   Liangjun Li,*a   Sifu Tang,b   Chao Wangb  and  Xuebo Zhao*ab  

* Corresponding authors

a Institute of Unconventional Hydrocarbon and New Energy Sources, China University of Petroleum (East China), Qingdao 266580, China
E-mail: liliangjun1982@hotmail.com

b Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, China
E-mail: zhaoxb@qibebt.ac.cn
Fax: +86 0532-80662728

Abstract

A metal–organic framework with chiral pores and decorated imidazole and methyl groups was constructed. Upon activation, this MOF undergoes a pore contraction and shows very high selectivity for CO2/N2 and CO2/CH4, indicating a synergistic effect of dynamic pores and functional groups.

Graphical abstract: High CO2/N2 and CO2/CH4 selectivity in a chiral metal–organic framework with contracted pores and multiple functionalities

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Article information

DOI
https://doi.org/10.1039/C4CC00334A
Article type
Communication
Submitted
15 Jan 2014
Accepted
02 Apr 2014
First published
02 Apr 2014

Chem. Commun., 2014,50, 6886-6889

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High CO2/N2 and CO2/CH4 selectivity in a chiral metal–organic framework with contracted pores and multiple functionalities

X. Lv, L. Li, S. Tang, C. Wang and X. Zhao, Chem. Commun., 2014, 50, 6886 DOI: 10.1039/C4CC00334A

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