Issue 29, 2014

Iron-catalyzed carbonylative Suzuki reactions under atmospheric pressure of carbon monoxide

Abstract

The first highly effective iron-catalyzed carbonylative Suzuki reaction has been developed. Substrates with electron-donating or electron-withdrawing functionality, ortho-substitution, as well as active groups proceeded smoothly, affording desired products in high yields. This protocol is economical, environmentally benign and practical for the synthesis of biaryl ketones.

Graphical abstract: Iron-catalyzed carbonylative Suzuki reactions under atmospheric pressure of carbon monoxide

Supplementary files

Article information

Article type
Communication
Submitted
26 Jan 2014
Accepted
18 Feb 2014
First published
18 Feb 2014

Chem. Commun., 2014,50, 3874-3877

Author version available

Iron-catalyzed carbonylative Suzuki reactions under atmospheric pressure of carbon monoxide

Y. Zhong and W. Han, Chem. Commun., 2014, 50, 3874 DOI: 10.1039/C4CC00688G

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