Issue 37, 2014

Novel binding regioselectivity in the interpenetration of a non-symmetric axle into a non-symmetric pillar[5]arene wheel

Abstract

We describe the regioselective complexation of a non-symmetric 5-bromovaleronitrile axle by a non-symmetric pillar[5]arene bearing different alkyl (methyl and pentyl) rims, forming an oriented interpenetrated complex with the directionality of CN@methyl rim and Br@pentyl rim.

Graphical abstract: Novel binding regioselectivity in the interpenetration of a non-symmetric axle into a non-symmetric pillar[5]arene wheel

Supplementary files

Article information

Article type
Communication
Submitted
29 Jan 2014
Accepted
27 Feb 2014
First published
27 Feb 2014

Chem. Commun., 2014,50, 4820-4823

Author version available

Novel binding regioselectivity in the interpenetration of a non-symmetric axle into a non-symmetric pillar[5]arene wheel

X. Shu, W. Chen, D. Hou, Q. Meng, R. Zheng and C. Li, Chem. Commun., 2014, 50, 4820 DOI: 10.1039/C4CC00800F

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