Issue 47, 2014
From the journal:

Chemical Communications

Alkyl transfer from C–C cleavage: replacing the nitro group of nitro-olefins†

Guangxun Li,a   Lei Wu,a   Gang Lv,a   Hongxin Liu,a   Qingquan Fu,a   Xiaomei Zhangb  and  Zhuo Tang*a  

* Corresponding authors

a Natural Products Research Center, Chengdu Institution of Biology, Chinese Academy of Science, Chengdu, Sichuan, China
E-mail: tangzhuo@cib.ac.cn

b Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu, Sichuan, China

Abstract

Alkyl substituted Hantzsch esters are rationally used as alkylation reagents to replace the nitro groups of nitro olefins to give excellent yields of trans-olefins. The reaction mechanism is considered to proceed through a free radical mechanism, which is different from the corresponding transfer alkylation of imines.

Graphical abstract: Alkyl transfer from C–C cleavage: replacing the nitro group of nitro-olefins

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Article information

DOI
https://doi.org/10.1039/C4CC01119H
Article type
Communication
Submitted
12 Feb 2014
Accepted
17 Mar 2014
First published
17 Mar 2014

Chem. Commun., 2014,50, 6246-6248

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Alkyl transfer from C–C cleavage: replacing the nitro group of nitro-olefins

G. Li, L. Wu, G. Lv, H. Liu, Q. Fu, X. Zhang and Z. Tang, Chem. Commun., 2014, 50, 6246 DOI: 10.1039/C4CC01119H

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