Issue 58, 2014
From the journal:

Chemical Communications

Boron–nitrogen substituted perylene obtained through photocyclisation†

Matthias Müller,a   Stefan Behnle,a   Cäcilia Maichle-Mössmerb  and  Holger F. Bettinger*a  

* Corresponding authors

a Institut für Organische Chemie, Universität Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany
E-mail: Holger.Bettinger@uni-tuebingen.de
Fax: +49-7071/29-5244
Tel: +49-7071/29-72072

b Institut für Anorganische Chemie, Universität Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany

Abstract

A BN substituted hexabenzotriphenylene (B3N3) closes one C–C-bond upon irradiation with light of 280–400 nm in the presence of iodine to yield a phenanthrene annelated B3N3 tribenzoperylene. Upon hydrolysis a B2N2 dibenzoperylene is obtained.

Graphical abstract: Boron–nitrogen substituted perylene obtained through photocyclisation

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Article information

DOI
https://doi.org/10.1039/C4CC01424C
Article type
Communication
Submitted
24 Feb 2014
Accepted
20 May 2014
First published
06 Jun 2014
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2014,50, 7821-7823

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Boron–nitrogen substituted perylene obtained through photocyclisation

M. Müller, S. Behnle, C. Maichle-Mössmer and H. F. Bettinger, Chem. Commun., 2014, 50, 7821 DOI: 10.1039/C4CC01424C

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