Issue 44, 2014

Metamagnetic behaviour in a new Cu(ii)Re(iv) chain based on the hexachlororhenate(iv) anion

Abstract

A new chloro-bridged heterobimetallic Cu(II)Re(IV) chain of formula {Cu(pyim)(Him)2ReCl6}n·MeCN (1·MeCN) has been prepared and magnetostructurally characterised. Compound 1 is the first example of the [ReIVCl6]2− anion acting as a metalloligand towards a paramagnetic metal ion.

Graphical abstract: Metamagnetic behaviour in a new Cu(ii)Re(iv) chain based on the hexachlororhenate(iv) anion

Supplementary files

Article information

Article type
Communication
Submitted
01 Mar 2014
Accepted
08 Apr 2014
First published
08 Apr 2014

Chem. Commun., 2014,50, 5840-5842

Metamagnetic behaviour in a new Cu(II)Re(IV) chain based on the hexachlororhenate(IV) anion

J. Martínez-Lillo, J. Kong, W. P. Barros, J. Faus, M. Julve and E. K. Brechin, Chem. Commun., 2014, 50, 5840 DOI: 10.1039/C4CC01564A

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