Issue 58, 2014
From the journal:

Chemical Communications

Iron(iii)–salan complexes catalysed highly enantioselective fluorination and hydroxylation of β-keto esters and N-Boc oxindoles†

Xin Gu,a   Yan Zhang,a   Zhen-Jiang Xu*a  and  Chi-Ming Che*ab  

* Corresponding authors

a Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, 354 Feng Lin Road, Shanghai, China
E-mail: xuzhenjiang@mail.sioc.ac.cn, cmche@hku.hk
Fax: +852 2857-1586
Tel: +852 2859-2154

b Department of Chemistry and State Key Laboratory of Synthetic Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, China

Abstract

Chiral iron(III)–salan complexes catalysed highly enantioselective α-fluorination and α-hydroxylation of β-keto esters and N-Boc oxindoles to give the corresponding products in high yields and good-to-excellent ee values under mild reaction conditions.

Graphical abstract: Iron(iii)–salan complexes catalysed highly enantioselective fluorination and hydroxylation of β-keto esters and N-Boc oxindoles

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Article information

DOI
https://doi.org/10.1039/C4CC01631A
Article type
Communication
Submitted
04 Mar 2014
Accepted
27 May 2014
First published
09 Jun 2014

Chem. Commun., 2014,50, 7870-7873

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Iron(III)–salan complexes catalysed highly enantioselective fluorination and hydroxylation of β-keto esters and N-Boc oxindoles

X. Gu, Y. Zhang, Z. Xu and C. Che, Chem. Commun., 2014, 50, 7870 DOI: 10.1039/C4CC01631A

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