Issue 62, 2014
From the journal:

Chemical Communications

Highly efficient and reversible iodine capture using a metalloporphyrin-based conjugated microporous polymer†

Sigen A,a   Yuwei Zhang,a   Zhongping Li,a   Hong Xia,b   Ming Xue,c   Xiaoming Liu*a  and  Ying Mua  

* Corresponding authors

a State Key Laboratory for Supramolecular Structure and Materials, College of Chemistry, Jilin University, 2699 Qianjin Avenue, Changchun, P.R. China
E-mail: xm_liu@jlu.edu.cn

b State Key Laboratory on Integrated Optoelectronics, College of Electronic Science and Technology, Jilin University, Changchun, P.R. China

c State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun, P.R. China

Abstract

A new metalloporphyrin-based conjugated microporous polymer, NiP-CMP, was constructed via a homo-coupling polymerization reaction. NiP-CMP possesses a high BET surface area of over 2600 m2 g−1, a large pore volume of 2.288 cm3 g−1, good stability, and displays excellent guest uptake of 202 wt% in iodine vapour. We also highlight that the polymer exhibits outstanding performance for the reversible adsorption of iodine in solution.

Graphical abstract: Highly efficient and reversible iodine capture using a metalloporphyrin-based conjugated microporous polymer

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C4CC01783H
Article type
Communication
Submitted
10 Mar 2014
Accepted
09 May 2014
First published
12 May 2014

Chem. Commun., 2014,50, 8495-8498

Author version available

Download author version (PDF)

Permissions

Request permissions

Highly efficient and reversible iodine capture using a metalloporphyrin-based conjugated microporous polymer

S. A, Y. Zhang, Z. Li, H. Xia, M. Xue, X. Liu and Y. Mu, Chem. Commun., 2014, 50, 8495 DOI: 10.1039/C4CC01783H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements