Issue 62, 2014

A unique copper-catalyzed cross-coupling reaction by hydrogen (H2) removal for the stereoselective synthesis of 3-phosphoindoles

Abstract

The first Cu(I)-catalyzed cross-coupling reaction by hydrogen (H2) removal for the stereoselective synthesis of 3-phosphoindoles is reported. Going beyond the oxidative dehydrogenative coupling reactions reported recently, this reaction completely omits the oxidant and base, producing hydrogen (H2) as the only byproduct.

Graphical abstract: A unique copper-catalyzed cross-coupling reaction by hydrogen (H2) removal for the stereoselective synthesis of 3-phosphoindoles

Supplementary files

Article information

Article type
Communication
Submitted
11 Mar 2014
Accepted
01 May 2014
First published
08 May 2014

Chem. Commun., 2014,50, 8529-8532

Author version available

A unique copper-catalyzed cross-coupling reaction by hydrogen (H2) removal for the stereoselective synthesis of 3-phosphoindoles

A. Zhou, L. Mao, G. Wang and S. Yang, Chem. Commun., 2014, 50, 8529 DOI: 10.1039/C4CC01815J

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