Issue 43, 2014
From the journal:

Chemical Communications

A silver(i) coordinated phenanthroline-based polymer with high ethylene/ethane adsorption selectivity†

Chao Yu,a   Matthew G. Cowan,b   Richard D. Nobleb  and  Wei Zhang*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of Colorado, Boulder, CO 80309, USA
E-mail: wei.zhang@colorado.edu

b Department of Chemical and Biological Engineering, University of Colorado, Boulder, CO 80309, USA

Abstract

We report a non-porous silver(I) coordinated phenanthroline-based polymer, which exhibits a high ideal ethylene/ethane adsorption selectivity (15/1) and high ethylene uptake (5.0 mmol gāˆ’1) at ambient temperature and pressure. Both silver(I) coordination and polymer structures are important for the high uptake of ethylene.

Graphical abstract: A silver(i) coordinated phenanthroline-based polymer with high ethylene/ethane adsorption selectivity

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Article information

DOI
https://doi.org/10.1039/C4CC02143F
Article type
Communication
Submitted
22 Mar 2014
Accepted
05 Apr 2014
First published
07 Apr 2014

Chem. Commun., 2014,50, 5745-5747

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A silver(I) coordinated phenanthroline-based polymer with high ethylene/ethane adsorption selectivity

C. Yu, M. G. Cowan, R. D. Noble and W. Zhang, Chem. Commun., 2014, 50, 5745 DOI: 10.1039/C4CC02143F

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