Issue 48, 2014
From the journal:

Chemical Communications

Iron-catalyzed alkylation of α-oxo ketene dithioacetals†

Qin Yang,a   Ping Wu,a   Jiping Chena  and  Zhengkun Yu*a  

* Corresponding authors

a Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, China
E-mail: zkyu@dicp.ac.cn
Fax: +86 411 8437 9227
Tel: +86 411 8437 9227

Abstract

Iron-catalyzed alkylation of internal olefins, that is, α-oxo ketene dithioacetals, was successfully realized by using styrenes as the alkylating reagents. Highly functionalized tetrasubstituted olefins were prepared in moderate to high yields.

Graphical abstract: Iron-catalyzed alkylation of α-oxo ketene dithioacetals

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Article information

DOI
https://doi.org/10.1039/C4CC02264E
Article type
Communication
Submitted
27 Mar 2014
Accepted
29 Apr 2014
First published
29 Apr 2014

Chem. Commun., 2014,50, 6337-6339

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Iron-catalyzed alkylation of α-oxo ketene dithioacetals

Q. Yang, P. Wu, J. Chen and Z. Yu, Chem. Commun., 2014, 50, 6337 DOI: 10.1039/C4CC02264E

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