Issue 57, 2014

Copper-catalysed oxidative Csp3–H methylenation to terminal olefins using DMF

Abstract

A copper-catalysed direct oxidative Csp3–H methylenation to terminal olefins using DMF as one carbon source was developed. In this reaction, various functional groups were well tolerated, thus providing a simple way to construct arylvinylketones and arylvinylpyridines. The preliminary mechanistic investigations revealed that CH2 was from DMF (N–CH3).

Graphical abstract: Copper-catalysed oxidative Csp3–H methylenation to terminal olefins using DMF

Supplementary files

Article information

Article type
Communication
Submitted
27 Mar 2014
Accepted
20 May 2014
First published
21 May 2014

Chem. Commun., 2014,50, 7636-7638

Author version available

Copper-catalysed oxidative Csp3–H methylenation to terminal olefins using DMF

J. Liu, H. Yi, X. Zhang, C. Liu, R. Liu, G. Zhang and A. Lei, Chem. Commun., 2014, 50, 7636 DOI: 10.1039/C4CC02275K

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