A spin-canted NiII4-based metal–organic framework with gas sorption properties and high adsorptive selectivity for light hydrocarbons

Jia Li; Ying Guo; Hong-Ru Fu; Jian Zhang; Rong-Bin Huang; Lan-Sun Zheng; Jun Tao

doi:10.1039/C4CC02396J

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A spin-canted Ni^II₄-based metal–organic framework with gas sorption properties and high adsorptive selectivity for light hydrocarbons†

Jia Li,^a Ying Guo,^a Hong-Ru Fu,^b Jian Zhang,^b Rong-Bin Huang,^a Lan-Sun Zheng^a and Jun Tao*^ac

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* Corresponding authors

^a State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, People's Republic of China
E-mail: taojun@xmu.edu.cn
Fax: +86-592-2183047
Tel: +86-592-2188138

^b Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science, Fuzhou 350002, People's Republic of China

^c Collaborative Innnovation Center of Chemistry for Energy Materials, Xiamen University, Xiamen 361005, People's Republic of China

Abstract

The reaction of nickel(II) nitrate with isonicotinic acid and 2,6-dimethyl-pyridine-3,5-dicarboxylic acid affords a novel, tetranuclear nickel(II)-based metal–organic framework that exhibits spin-canted antiferromagnetism with a canted angle of 1.65° and high adsorptive selectivity for light hydrocarbons.

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Article information

DOI: https://doi.org/10.1039/C4CC02396J
Article type: Communication
Submitted: 01 Apr 2014
Accepted: 27 Jun 2014
First published: 27 Jun 2014

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Chem. Commun., 2014,50, 9161-9164

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A spin-canted Ni^II₄-based metal–organic framework with gas sorption properties and high adsorptive selectivity for light hydrocarbons

J. Li, Y. Guo, H. Fu, J. Zhang, R. Huang, L. Zheng and J. Tao, Chem. Commun., 2014, 50, 9161 DOI: 10.1039/C4CC02396J

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Chemical Communications