Issue 64, 2014
From the journal:

Chemical Communications

Entrapment of alkaloids within silver: from enantioselective hydrogenation to chiral recognition†

Hengpan Yang,a   Dinghui Chi,a   Qilong Sun,a   Wenwen Sun,a   Huan Wang*a  and  Jiaxing Lu*a  

* Corresponding authors

a Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062, China
E-mail: hwang@chem.ecnu.edu.cn, jxlu@chem.ecnu.edu.cn
Tel: +86-21-52134935

Abstract

An alkaloid@Ag composite was prepared for the first time and used as a cathode for the enantioselective hydrogenation. Excellent yield and a remarkable enantiomeric excess value were obtained under mild conditions. Moreover, alkaloid@Ag after extraction was demonstrated to retain some chirality by linear sweep voltammetry.

Graphical abstract: Entrapment of alkaloids within silver: from enantioselective hydrogenation to chiral recognition

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Article information

DOI
https://doi.org/10.1039/C4CC02823F
Article type
Communication
Submitted
16 Apr 2014
Accepted
16 Jun 2014
First published
16 Jun 2014

Chem. Commun., 2014,50, 8868-8870

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Entrapment of alkaloids within silver: from enantioselective hydrogenation to chiral recognition

H. Yang, D. Chi, Q. Sun, W. Sun, H. Wang and J. Lu, Chem. Commun., 2014, 50, 8868 DOI: 10.1039/C4CC02823F

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