Issue 89, 2014
From the journal:

Chemical Communications

A nanoporous Ag(i)-MOF showing unique selective adsorption of benzene among its organic analogues†

Jun-Yan Cheng,a   Peng Wang,ab   Jian-Ping Ma,a   Qi-Kui Liua  and  Yu-Bin Dong*a  

* Corresponding authors

a College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Normal University, Jinan 250014, P. R. China
E-mail: yubindong@sdnu.edu.cn

b College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, People's Republic of China

Abstract

A stable porous Ag(I)-MOF with new topology is constructed from AgSbF6 and 3,6-bis[2-(4-oxide-quinoxaline)-yl]-4,5-diaza-3,5-octadiene (L). This compound can be a highly selective porous MOF material to effectively separate benzene from its six-membered cyclic organic analogues such as cyclohexane, cyclohexene and o-, m-, p-xylene under ambient conditions in both vapor and liquid phases.

Graphical abstract: A nanoporous Ag(i)-MOF showing unique selective adsorption of benzene among its organic analogues

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Article information

DOI
https://doi.org/10.1039/C4CC03204G
Article type
Communication
Submitted
29 Apr 2014
Accepted
17 Jun 2014
First published
18 Jun 2014

Chem. Commun., 2014,50, 13672-13675

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A nanoporous Ag(I)-MOF showing unique selective adsorption of benzene among its organic analogues

J. Cheng, P. Wang, J. Ma, Q. Liu and Y. Dong, Chem. Commun., 2014, 50, 13672 DOI: 10.1039/C4CC03204G

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