Allylic sp3 C–H borylation of alkenes via allyl-Pd intermediates: an efficient route to allylboronates

Hong-Ping Deng; Lars Eriksson; Kálmán J. Szabó

doi:10.1039/C4CC04151H

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Allylic sp³ C–H borylation of alkenes via allyl-Pd intermediates: an efficient route to allylboronates†

Hong-Ping Deng,^a Lars Eriksson^b and Kálmán J. Szabó*^a

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* Corresponding authors

^a Department of Organic Chemistry, Stockholm University, Sweden

^b Department of Inorganic and Structural Chemistry, Stockholm University, Sweden
E-mail: kalman@organ.su.se
Web: http://www.organ.su.se/ks/
Fax: +46-8-15 49 08

Abstract

Palladium catalyzed allylic C–H functionalization was performed using exocyclic alkene substrates. Multi-component synthesis of stereodefined homoallylic alcohols could be performed using a reaction sequence involving allylic C–H borylation and allylation of aldehydes.

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Supplementary files

Crystal structure data CIF (21K)

Article information

DOI: https://doi.org/10.1039/C4CC04151H
Article type: Communication
Submitted: 30 May 2014
Accepted: 26 Jun 2014
First published: 26 Jun 2014
This article is Open Access

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Chem. Commun., 2014,50, 9207-9210

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Allylic sp³ C–H borylation of alkenes via allyl-Pd intermediates: an efficient route to allylboronates

H. Deng, L. Eriksson and K. J. Szabó, Chem. Commun., 2014, 50, 9207 DOI: 10.1039/C4CC04151H

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