Issue 67, 2014

Guest control of structure in porous organic cages

Abstract

Two porous organic cages with different thermodynamic polymorphs were induced by co-solvents to interchange their crystal packing modes, thus achieving guest-mediated control over solid-state porosity. In situ crystallography allows the effect of the co-solvent guests on these structural interconversions to be understood.

Graphical abstract: Guest control of structure in porous organic cages

Supplementary files

Article information

Article type
Communication
Submitted
30 May 2014
Accepted
25 Jun 2014
First published
10 Jul 2014
This article is Open Access
Creative Commons BY license

Chem. Commun., 2014,50, 9465-9468

Author version available

Guest control of structure in porous organic cages

M. A. Little, S. Y. Chong, M. Schmidtmann, T. Hasell and A. I. Cooper, Chem. Commun., 2014, 50, 9465 DOI: 10.1039/C4CC04158E

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