Issue 76, 2014
From the journal:

Chemical Communications

Local protonation control using plasmonic activation†

Pushkar Singha  and  Volker Deckert*ab  

* Corresponding authors

a Leibniz Institute of Photonic Technology, Albert-Einstein-Str. 9, 07745 Jena, Germany

b Institute of Physical Chemistry and Abbe Center of Photonics, Friedrich-Schiller University Jena, Helmholtzweg 4, 07743 Jena, Germany
E-mail: volker.deckert@ipht-jena.de

Abstract

Localized protonation of 4-mercaptopyridine (4-MPY), activated by light in the presence of silver nanoparticles is monitored under ambient conditions using surface-enhanced Raman scattering (SERS) and tip-enhanced Raman scattering (TERS). The reaction can be controlled by the excitation wavelength and the atmospheric conditions, thus, providing a tool for site-specific control of protonation.

Graphical abstract: Local protonation control using plasmonic activation

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Article information

DOI
https://doi.org/10.1039/C4CC04642K
Article type
Communication
Submitted
18 Jun 2014
Accepted
05 Aug 2014
First published
05 Aug 2014
This article is Open Access
Creative Commons BY license

Chem. Commun., 2014,50, 11204-11207

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Local protonation control using plasmonic activation

P. Singh and V. Deckert, Chem. Commun., 2014, 50, 11204 DOI: 10.1039/C4CC04642K

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