Issue 79, 2014

Classical and non-classical redox reactions of Pd(ii) complexes containing redox-active ligands

Abstract

Reactivity studies of a Pd(II)–verdazyl complex reveal novel ligand-centred reduction processes which trigger pseudo-reductive elimination at Pd. Reaction of the complex with water induces a ligand-centred redox disproportionation. The reduced verdazyl ligands can also be reversibly protonated.

Graphical abstract: Classical and non-classical redox reactions of Pd(ii) complexes containing redox-active ligands

Supplementary files

Article information

Article type
Communication
Submitted
26 Jun 2014
Accepted
06 Aug 2014
First published
08 Aug 2014

Chem. Commun., 2014,50, 11676-11678

Classical and non-classical redox reactions of Pd(II) complexes containing redox-active ligands

C. A. Sanz, M. J. Ferguson, R. McDonald, B. O. Patrick and R. G. Hicks, Chem. Commun., 2014, 50, 11676 DOI: 10.1039/C4CC04863F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements