A highly Lewis-acidic Pd(iv) surface on Pd@SiO2 nanocatalysts for hydroalkoxylation reactions

Abstract

The Pd(IV) species, known to be critical intermediates in homogeneous catalysis, were successfully generated on the surface of Pd nanocatalysts via oxidation with iodobenzene dichloride (PhICl₂) or N-chlorosuccinimide (NCS). In particular, the Pd@SiO₂ yolk–shell nanocatalyst activated by PhICl₂ showed high reactivity and superior stability to the other Pd-based catalysts for hydroalkoxylation reactions even at 25 °C.