Issue 88, 2014

N-Methylation of amine and nitro compounds with CO2/H2 catalyzed by Pd/CuZrOx under mild reaction conditions

Abstract

An active Pd/ZrCuOx catalyst was prepared for the reductive amination of CO2. The N-methylation of amines and nitro compounds with CO2/H2 can be realized with up to 97% yield under relatively mild reaction conditions. N-Formylation becomes the main reaction if the reaction was performed under milder conditions or using Pd/ZnZrOx as the catalyst.

Graphical abstract: N-Methylation of amine and nitro compounds with CO2/H2 catalyzed by Pd/CuZrOx under mild reaction conditions

Supplementary files

Article information

Article type
Communication
Submitted
03 Jul 2014
Accepted
04 Sep 2014
First published
09 Sep 2014

Chem. Commun., 2014,50, 13521-13524

N-Methylation of amine and nitro compounds with CO2/H2 catalyzed by Pd/CuZrOx under mild reaction conditions

X. Cui, Y. Zhang, Y. Deng and F. Shi, Chem. Commun., 2014, 50, 13521 DOI: 10.1039/C4CC05119J

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