Issue 84, 2014

Alkaline earth catalysis for the 100% atom-efficient three component assembly of imidazolidin-2-ones

Abstract

A variety of functionalised imidazolidin-2-ones may be synthesised under very mild reaction conditions using non-toxic and cost-effective alkaline earth bis(amide) pre-catalysts in a 100% atom-efficient, intermolecular one-pot assembly from inexpensive alkyne and cumulene reagents.

Graphical abstract: Alkaline earth catalysis for the 100% atom-efficient three component assembly of imidazolidin-2-ones

Supplementary files

Article information

Article type
Communication
Submitted
07 Jul 2014
Accepted
04 Sep 2014
First published
05 Sep 2014

Chem. Commun., 2014,50, 12676-12679

Author version available

Alkaline earth catalysis for the 100% atom-efficient three component assembly of imidazolidin-2-ones

M. Arrowsmith, W. M. S. Shepherd, M. S. Hill and G. Kociok-Köhn, Chem. Commun., 2014, 50, 12676 DOI: 10.1039/C4CC05223D

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