Issue 73, 2014

Highly-metallized phosphonium polyelectrolytes

Abstract

The synthesis and characterization of a novel class of highly-metallized, redox-active polyelectrolytes that employ phosphorus as a scaffold for the installation of transition metals is described. Pyrolysis of thin films of the title polyelectrolytes resulted in the production of magnetite crystallites and ill-defined carbon-, phosphorus- and oxygen-rich phases in char yields of nearly 50%.

Graphical abstract: Highly-metallized phosphonium polyelectrolytes

Supplementary files

Article information

Article type
Communication
Submitted
09 Jul 2014
Accepted
22 Jul 2014
First published
01 Aug 2014

Chem. Commun., 2014,50, 10714-10717

Author version available

Highly-metallized phosphonium polyelectrolytes

A. Rabiee Kenaree, B. M. Berven, P. J. Ragogna and J. B. Gilroy, Chem. Commun., 2014, 50, 10714 DOI: 10.1039/C4CC05296J

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