Stepwise assembly of an adamantoid Ru4Ag6 cage by control of metal coordination geometry at specific sites

Abstract

The geometrically pure ‘complex ligand’ fac-[Ru(L^ph)₃]²⁺, in which three pendant bidentate binding sites are located on one face of the complex, reacts with Ag(I) ions to form the adamantoid decanuclear cage [{Ru(L^ph)₃}₄Ag₆](PF₆)₁₄ which contains a 6-coordinate Ru(II) ion at each vertex of a large tetrahedron and a 4-coordinate Ag(I) ion along each edge.