Issue 97, 2014
From the journal:

Chemical Communications

Highly regio- and stereoselective nitro-oxoamination of mono-substituted allenes†

Can Xue,a   Chunling Fu*a  and  Shengming Ma*a  

* Corresponding authors

a Laboratory of Molecular Recognition and Synthesis Department of Chemistry, Zhejiang University, Hangzhou 310027, Zhejiang, People's Republic of China
E-mail: masm@sioc.ac.cn
Fax: +86-21-626-09305
Tel: +86-21-622-37360

Abstract

A highly regio- and stereoselective (up to 99/1) nitro-oxoamination reaction of mono-substituted allene occurs under mild conditions with readily available AgNO2 and a free radical trap TEMPO to form one C–N bond and one C–O bond in one step. Various functional groups and heterocycles could be tolerated in this conversion.

Graphical abstract: Highly regio- and stereoselective nitro-oxoamination of mono-substituted allenes

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Article information

DOI
https://doi.org/10.1039/C4CC05743K
Article type
Communication
Submitted
24 Jul 2014
Accepted
29 Sep 2014
First published
22 Oct 2014

Chem. Commun., 2014,50, 15333-15336

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Highly regio- and stereoselective nitro-oxoamination of mono-substituted allenes

C. Xue, C. Fu and S. Ma, Chem. Commun., 2014, 50, 15333 DOI: 10.1039/C4CC05743K

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