Issue 79, 2014

Organocatalytic amination of alkyl ethers via n-Bu4NI/t-BuOOH-mediated intermolecular oxidative C(sp3)–N bond formation: novel synthesis of hemiaminal ethers

Abstract

A novel method for constructing the hemiaminal ether framework under metal-free conditions has been developed. It involves direct organocatalytic amination of alkyl ethers through intermolecular oxidative C(sp3)–N bond formation, with t-BuOOH being the oxidant and n-Bu4NI as the catalyst.

Graphical abstract: Organocatalytic amination of alkyl ethers via n-Bu4NI/t-BuOOH-mediated intermolecular oxidative C(sp3)–N bond formation: novel synthesis of hemiaminal ethers

Supplementary files

Article information

Article type
Communication
Submitted
24 Jul 2014
Accepted
12 Aug 2014
First published
13 Aug 2014

Chem. Commun., 2014,50, 11738-11741

Author version available

Organocatalytic amination of alkyl ethers via n-Bu4NI/t-BuOOH-mediated intermolecular oxidative C(sp3)–N bond formation: novel synthesis of hemiaminal ethers

L. Dian, S. Wang, D. Zhang-Negrerie, Y. Du and K. Zhao, Chem. Commun., 2014, 50, 11738 DOI: 10.1039/C4CC05758A

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