A bimodal anionic MOF: turn-off sensing of CuII and specific sensitization of EuIII

Sohini Bhattacharyya; Anindita Chakraborty; Kolleboyina Jayaramulu; Arpan Hazra; Tapas Kumar Maji

doi:10.1039/C4CC05991C

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

A bimodal anionic MOF: turn-off sensing of Cu^II and specific sensitization of Eu^III†

Sohini Bhattacharyya,^a Anindita Chakraborty,^a Kolleboyina Jayaramulu,^a Arpan Hazra^a and Tapas Kumar Maji*^a

Author affiliations

* Corresponding authors

^a Molecular Materials Laboratory, Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore 560 064, India
E-mail: tmaji@jncasr.ac.in

Abstract

A novel porous anionic MOF {[Mg₃(ndc)_2.5(HCO₂)₂(H₂O)][NH₂Me₂]·2H₂O·DMF} (1) having exchangeable dimethyl amine cations in 1D channels has been synthesized and characterized. Through cation exchange, 1 manifests bimodal functionality, being a turn-off sensor of Cu^II on one hand, and a selective sensitizer of Eu^III emitting intense pure red emission on the other.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C4CC05991C
Article type: Communication
Submitted: 31 Jul 2014
Accepted: 09 Sep 2014
First published: 10 Sep 2014

Download Citation

Chem. Commun., 2014,50, 13567-13570

Author version available

Download author version (PDF)

Permissions

Request permissions

A bimodal anionic MOF: turn-off sensing of Cu^II and specific sensitization of Eu^III

S. Bhattacharyya, A. Chakraborty, K. Jayaramulu, A. Hazra and T. K. Maji, Chem. Commun., 2014, 50, 13567 DOI: 10.1039/C4CC05991C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications