Issue 88, 2014

Thermodynamics of halogen bonded monolayer self-assembly at the liquid–solid interface

Abstract

Monolayer self-assembly of a hexabrominated, three-fold symmetric aromatic molecule is studied at the heptanoic acid–graphite interface. Thermodynamical insights are obtained from an adapted Born–Haber cycle that is utilized to derive the overall enthalpy change including solvent effects. Comparison with theoretical entropy estimates suggests a minor influence of solvation.

Graphical abstract: Thermodynamics of halogen bonded monolayer self-assembly at the liquid–solid interface

Supplementary files

Article information

Article type
Communication
Submitted
09 Aug 2014
Accepted
08 Sep 2014
First published
09 Sep 2014

Chem. Commun., 2014,50, 13465-13468

Author version available

Thermodynamics of halogen bonded monolayer self-assembly at the liquid–solid interface

W. Song, N. Martsinovich, W. M. Heckl and M. Lackinger, Chem. Commun., 2014, 50, 13465 DOI: 10.1039/C4CC06251E

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