Issue 25, 2015

Redox-induced fluoride ligand dissociation stabilized by intramolecular hydrogen bonding

Abstract

Chemical reduction of a tripodal Cu(II)–F complex containing pendent hydroxyl groups results in the partial dissociation of a F ligand from Cu. The resulting Cu(I) complex is characterized as containing an outer sphere F anion ‘captured’ by hydrogen bonds. The pendent hydroxyl groups were found to be crucial for reductive stability.

Graphical abstract: Redox-induced fluoride ligand dissociation stabilized by intramolecular hydrogen bonding

Supplementary files

Article information

Article type
Communication
Submitted
29 Aug 2014
Accepted
28 Sep 2014
First published
06 Oct 2014

Chem. Commun., 2015,51, 5490-5492

Author version available

Redox-induced fluoride ligand dissociation stabilized by intramolecular hydrogen bonding

C. M. Moore and N. K. Szymczak, Chem. Commun., 2015, 51, 5490 DOI: 10.1039/C4CC06832G

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