Issue 91, 2014
From the journal:

Chemical Communications

Copper-mediated oxidative trifluoromethylthiolation of unactivated terminal alkenes†

Ke Zhang,a   Jian-Bo Liub  and  Feng-Ling Qing*ab  

* Corresponding authors

a College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, 2999 North Renmin Road, Shanghai 201620, China

b Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Science, 345 Lingling Road, Shanghai 200032, China
E-mail: flq@mail.sioc.ac.cn

Abstract

A general method to form a C(SP3)–SCF3 bond via copper-mediated oxidative trifluoromethylthiolation of unactivated alkenes with stable nucleophilic AgSCF3 was developed. This protocol provides a direct and efficient access to a series of trifluoromethylthiolated allylic compounds with broad functional group tolerance.

Graphical abstract: Copper-mediated oxidative trifluoromethylthiolation of unactivated terminal alkenes

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Article information

DOI
https://doi.org/10.1039/C4CC07062C
Article type
Communication
Submitted
07 Sep 2014
Accepted
22 Sep 2014
First published
03 Oct 2014

Chem. Commun., 2014,50, 14157-14160

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Copper-mediated oxidative trifluoromethylthiolation of unactivated terminal alkenes

K. Zhang, J. Liu and F. Qing, Chem. Commun., 2014, 50, 14157 DOI: 10.1039/C4CC07062C

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