SCHEDULED MAINTENANCE
A thiol-selective 2-methyl-3-phenacrylate scaffold with spatiotemporal control over delivery of a cargo is reported. The half-lives of decomposition could be tuned from 30 min to 1 day and the scaffold's utility in thiol-inducible fluorophore release in cell-free as well as within cells is demonstrated.
R. K. Sankar, R. S. Kumbhare, A. T. Dharmaraja and H. Chakrapani, Chem. Commun., 2014, 50, 15323 DOI: 10.1039/C4CC07343F
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