Issue 1, 2015
From the journal:

Chemical Communications

[Me2C{SnCH(SiMe3)2}2]2. A μ-Me2C-bridged tetrastanna tetrahedrane†‡

Michael Wagner,a   Michael Lutter,a   Bernhard Zobel,a   Wolf Hiller,a   Marc H. Prosencb  and  Klaus Jurkschat*a  

* Corresponding authors

a Lehrstuhl für Anorganische Chemie II, Technische Universität Dortmund, 44221 Dortmund, Germany
E-mail: klaus.jurkschat@tu-dortmund.de
Fax: +49 231 755 5048
Tel: +49 231 755 3800

b Physikalische Chemie, TU Kaiserslautern, Germany

Abstract

A spacer-bridged bis(organostannylene) was obtained. In the solid-state it adopts the structure of a doubly-capped tetrahedron. It reacts with elemental oxygen, O2, giving tin suboxides. Additionally, the first solid state structure of a spacer-bridged diorgano tin dihydride is reported.

Graphical abstract: [Me2C{SnCH(SiMe3)2}2]2. A μ-Me2C-bridged tetrastanna tetrahedrane

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Article information

DOI
https://doi.org/10.1039/C4CC07417C
Article type
Communication
Submitted
19 Sep 2014
Accepted
05 Nov 2014
First published
06 Nov 2014

Chem. Commun., 2015,51, 153-156

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[Me2C{SnCH(SiMe3)2}2]2. A μ-Me2C-bridged tetrastanna tetrahedrane

M. Wagner, M. Lutter, B. Zobel, W. Hiller, M. H. Prosenc and K. Jurkschat, Chem. Commun., 2015, 51, 153 DOI: 10.1039/C4CC07417C

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