Issue 1, 2015

Ammonium iodide-induced sulfonylation of alkenes with DMSO and water toward the synthesis of vinyl methyl sulfones

Abstract

A novel ammonium iodide-induced sulfonylation of alkenes with DMSO and water toward the synthesis of vinyl methyl sulfones is described. The process proceeded smoothly under metal-free conditions with high stereoselectivity and good functional group tolerance. The reaction mechanism was revealed to proceed through a domino reaction of oxidation and elimination after the radical addition to alkenes.

Graphical abstract: Ammonium iodide-induced sulfonylation of alkenes with DMSO and water toward the synthesis of vinyl methyl sulfones

Supplementary files

Article information

Article type
Communication
Submitted
26 Sep 2014
Accepted
02 Nov 2014
First published
04 Nov 2014

Chem. Commun., 2015,51, 210-212

Author version available

Ammonium iodide-induced sulfonylation of alkenes with DMSO and water toward the synthesis of vinyl methyl sulfones

X. Gao, X. Pan, J. Gao, H. Huang, G. Yuan and Y. Li, Chem. Commun., 2015, 51, 210 DOI: 10.1039/C4CC07606K

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